Home Chemistry Chemical Equilibrium JEE Advanced Previous Years Question 5.1 g NH 4 SH is introduced in 3.0 L evacuat…
Chemistry Chemical Equilibrium JEE Advanced Previous Years Question Single Correct MCQ
Published on: August 14, 2026

5.1 g NH 4 SH is introduced in 3.0 L evacuated flask at 327°C. 30% of the solid NH 4 SH decomposed to NH 3 and H 2 S as gases. The K p of the reaction at 327°C is (R = 0.082 L atm mol –1 K –1 , molar mass of S = 32 g mol –1 , molar mass of N = 14 g mol –1 )

A
4.9 × 10 –3 atm 2
B
0.242 × 10 –4 atm 2
C
1 × 10 –4 atm 2
D
0.242 atm 2

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Verified by Experts
The correct answer is:
D

NH 4 HS H 2 S + NH 3

0.1(1–0.3) 0.03 0.03

K C =

K P = K C (RT) Δ n

= 10 –4 × (0.0821 × 600) 2 = 0.242

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